Germanium disulfide

Germanium disulfide
Identifiers
CAS number 12025-34-2 Y
PubChem 82816
ChemSpider 74732 Y
EC number 234-705-1
Jmol-3D images Image 1
Properties
Molecular formula GeS2
Molar mass 136.77 g mol−1
Exact mass 137.865319593 g mol-1
Appearance White, translucent crystals
Density 2.94 g cm-3
Melting point

800 °C, 1073 K, 1472 °F

Structure
Crystal structure monoclinic, mP36
Space group Pc, No. 7
Coordination
geometry
tetrahedral at Ge, bent at S
Related compounds
Related compounds Carbon disulfide

Germanium dioxide
Germanium diselenide
Germanium monosulfide
Lead disulfide
Silicon sulfide
Tin disulfide

 Y (verify) (what is: Y/N?)
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Infobox references

Germanium disulfide refers to the chemical compound with the formula GeS2. It is a colourless white crystalline material, which melts at roughly 800 °C.[1][2]

History

Germanium sulfide was the first germanium compound found by Clemens Winkler during the analysis of argyrodite. The fact that germanium sulfide is not soluble in acidic water made it possible for Winkler to isolate the new element from the other elements.[3]

References

  1. ^ Otto H. Johnson (1952). "Germanium and its Inorganic Compounds". Chem. Rev. 3: 431. doi:10.1021/cr60160a002. 
  2. ^ A. V. Golubkov, G. B. Dubrovskii and A. I. Shelykh (1998). "Preparation and properties of GeS2 single crystals". Semiconductors 32 (7): 734–735. doi:10.1134/1.1187494. 
  3. ^ Clemens Winkler (1886). "Mittheilungen über das Germanium". J. Prak. Chemie 34: 177–229. doi:10.1002/prac.18860340122. http://gallica.bnf.fr/ark:/12148/bpt6k90797z/f185.table.